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21.
Nandini Kumar U. C. Kulshrestha A. Saxena P. Khare K. M. Kumari S. S. Srivastava 《Journal of Atmospheric Chemistry》1996,23(1):81-87
A total of 59 rainwater samples were collected during the winter and monsoon (1991–92) at Dayalbagh, Agra. This site is relatively free from the influence of anthropogenic emissions and the volume-weighted average concentrations (VWA) of formate in the winter and monsoon were 22.5±6, 16.1±3 while acetate VWAs were 17.1±5 and 13.8±3 mol l-1, respectively. Although the VWAs varied between seasons, it was not statistically different. Total deposition (in mmol m-2) varied between season (winter formate, 1.4; acetate, 1.1; monsoon formate, 7.4; acetate, 6.4). A difference in VWA values may have occurred as a result of the dilution factor; the total rain depth from collected samples in the monsoon was 46 cm while that in winter was 6.3 cm. Sources at this site may be anthropogenic and natural; scavenging from the vapour phase, washout of soil particles and emissions from vegetative sources are probably important sources for formate and acetate. 相似文献
22.
研究了四片藻 (Tetraselmissp.)利用无机碳、氮源生长的情况 ,结果表明 ,四片藻以利用乙酸盐和脲生长最好 ,其最佳浓度分别为 1 .2g·L- 1 和 0 .6g·L- 1 。以总脂和脂肪酸组成为例 ,比较了基本培养基、有机碳、氮源培养基和无机碳、氮源培养基对四片藻生长和生化组成的影响 ,结果表明 ,在光培养条件下 ,上述各培养基对四片藻生长的影响差别很大 ,培养 7d ,有机和无机碳、氮源培养基中的细胞浓度分别为基本培养基中细胞浓度的 3.2倍和 2 .4倍 ;总脂含量以添加有机或无机碳、氮源培养基的较高 ,分别占细胞干重的 9.7%和 1 0 .3 % ;上述各培养基对脂肪酸组成与含量的影响差别不大。 相似文献
23.
The formation of products following the hydroxyl radical initiated photo-oxidations of n-and isopropyl acetates has been studied. Mixtures of synthetic air containing a few ppm of nitrous acid, nitric oxide, nitrogen dioxide and one of the propyl acetates were irradiated with sunlamps in a Teflon bag smog chamber. The decay of reactants and the formation of products was monitored by chemiluminescent analysis or by gas chromatography. The major primary products from the photo-oxidation of n-propyl acetate are acetaldehyde and propionaldehyde while from isopropyl acetate they are acetone and methyl nitrate. It was not possible to analyse for formaldehyde, an expected primary product in these systems. The nature and distribution of products indicate that a significant fraction of primary products arise from decomposition reactions of the alkoxy-type radicals generated following the initial attack of hydroxyl radicals on the esters. The derived reaction stoichiometries (molecules of NO oxidised per molecule of ester reacted) are also consistent with the proposed mechanisms. 相似文献
24.
Puja Khare S. P. Singh K. Maharaj Kumari Ashok Kumar S. S. Srivastava 《Journal of Atmospheric Chemistry》2000,37(3):231-244
Levels of formate and acetate in dew were measured at Dayalbagh, India, usingsurrogate surfaces. The dew formed per night ranged between 0.06 lm–2 and 1.38 l m–2, with an average of 0.59l m–2. pH ranged between 6.7 and 7.4. Mean concentrations offormate and acetate in dew were 10.2 ± 10.2 eql–1 and 7.5 ± 4.5 eq l–1,respectively. The correlation coefficient between the two ions was 0.80 (p =0.001), which suggested that concentrations of these species in dew are linkedtogether. They have either common or different sources with fairly constantstrengths or products of same reaction. Good correlation of formate andacetate with Ca (r = 0.82 and r = 0.70, respectively) and Mg (r = 0.74 and r= 0.71, respectively) suggested that these ions may be associated with Ca andMg after the neutralization process. Deposition rates for formate and acetatein dew per night were 10.2 ± 7.22 mol m–2 pernight and 4.6 ± 2.2 mol m–2 per night,respectively. The theoretical Henry's law constant (K*
H)and the field-observed Henry's law coefficient (K*
H) ascalculated from concurrent measurements of gas phase and dew for both acidsshowed large discrepancies of three orders of magnitude. 相似文献
25.
26.
在醋酸－醋酸钠－铜铁试剂一二苯胍体系中对微量铀进行极谱测定。在峰电位为－１．１７Ｖ，铀浓度在０．０５μｇ·ｍＬ￣（－１）－２μｇ·ｍＬ￣（－１）之间时铀的浓度与峰电流成线性关系。本方法选用碳酸铵小体积沉淀分离干扰元素，直接取其清液测定微量铀。最低检出限为０．０２μｇ·ｍＬ￣（－１）。 相似文献
27.
Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan basins in Yunnan Province, China 总被引：2，自引：1，他引：2
XU Yongchang LIU Wenhui SHEN Ping WANG Wanchun WANG Xiaofeng Tenger YAN Yaomin & LIU Ruobin . Lanzhou Center of Oil & Gas Resources Institute of Geology Geophsics Chinese Academy of Sciences Lanzhou China . Research Institute of Petroleum Exploration Production SINOPEC Beijing China . South Branch of Petroleum Exploration Production Company SINOPEC Kuming China 《中国科学D辑(英文版)》2006,49(9):938-946
The Luliang and Baoshan basins are two small ba- sins in Yunnan Province. In the recent ten years or so, there have been found a number of natural gas pools of commercial importance in the two basins. Although the gas pools are small in size, the natural … 相似文献
28.
古里雅冰芯中生物有机酸的初步分析 总被引：9，自引：3，他引：6
甲酸、乙酸是全球对流层中普遍存在的化学成分,它们对偏远地区降水中的酸度有很大影响,降水中存在的甲酸、乙酸必然会在冰川和冰盖中保存下来．然而,目前很少有文章报道山地冰川中甲酸、乙酸的测定结果及环境意义．我们用离子色谱法测定了古里雅上部５ｍ冰芯中甲酸、乙酸的浓度,结果显示,甲酸、乙酸具有明显的季节变化,峰值一般对应于夏季层位,说明甲酸、乙酸的来源不同于阳离子,粉尘不是其主要来源．将甲酸、乙酸的记录与冰芯中δ１８Ｏ和阳离子的记录对比,得出甲酸具有较敏感的气候指示意义． 相似文献
29.
为研究小球藻(Chlorella vulgaris)对不同浓度Fe~(3+)的响应,测定了自养和乙酸兼养小球藻在不同浓度Fe~(3+)条件下的生长速率和油脂含量,比较分析了兼养小球藻在不同浓度Fe~(3+)下的蛋白质组表达差异。结果表明,兼养小球藻比自养小球藻生长速率快,积累的生物量多,在缺铁条件下中性脂含量高。蛋白质组分析显示:在缺铁条件下光合作用相关蛋白含量最低;在缺铁和高浓度铁条件下,热激蛋白、蛋白合成和糖代谢等过程相关蛋白表达都下调,表明缺铁和高浓度铁条件对小球藻的生长都是逆境条件;在缺铁条件下氨基酸代谢相关蛋白表达上调,这可能是由于NO_3~–同化下降,氨基酸合成减少,需要进行氮的回收利用。上述结果表明:在兼养条件下缺铁培养的小球藻可获得较高生物量和中性脂含量;而高浓度铁能促进小球藻生长,但不能提高中性脂含量,对藻细胞也有一定的胁迫效应。 相似文献
30.
Used extensively in exploration geology to simulate the natural weathering of mineral deposits, sequential extractions have found new use in environmental studies determining the processes governing metal transport in the environment as well as estimating the bioavailability of contaminants in soils, sediments and waste materials. Many extracting solutions and extraction sequences can be found in the literature and the abilities of any given extracting solution to solubilise a target component of a soil/sediment system is much debated. A study into the mechanisms of aqueous metal uptake by bauxite refinery residues (red mud) revealed the need to establish the selectivity of the sodium acetate solution used to extract metals from carbonates, an extracting solution common to most sequential extraction schemes. The phase extractability of copper and lead removed from solution by hydroxide and carbonate compounds was used to demonstrate and define the abilities of the sodium acetate extracting solution. The experiments in this study demonstrate that 1 M Na acetate, pH 5, also releases metals associated with hydroxide minerals. The impact of these findings will depend on the chemistry and mineralogy of the soil/sediment system or waste material studied. 相似文献